Get the complete project »
- The Complete Research Material is averagely 130 pages long and it is in Ms Word Format, it has 1-5 Chapters.
- Major Attributes are Abstract, All Chapters, Figures, Appendix, References.
- Study Level: BTech, BSc, BEng, BA, HND, ND or NCE.
- Full Access Fee: ₦7,000
The absorptive nature of S by plants depends on desorption of S from soils. Understanding the kinetics desorption of sulphate as influenced by parent materials and biochar is critical for effective precision of S diagnosis and fertilization recommendations to ensure sustainable and profitable crop production and environmental protection. In this study, soils derived from three (3) different parent materials namely; Chad formation (CF), Basement complex rock (BCR) and Kerri-Kerri formation (KKF) in the Sudan savanna and biochar soils were investigated on the kinetics of sulphate desorption behaviour. In the desorption experiment, soils were allowed to adsorb sulphate as in the adsorption studies and the adsorbed sulphate was extracted by shaking for 30, 60, 150, 180 and 240 minutes with 15 ml Ca(H2PO4)2 solution containing 500 mg P L-1 respectively. Five kinetic models first-order, second-order, Elovich, fractional power and parabolic diffusion models were used to test best model for describing S desorption in the soils of varying parent materials. Results indicated that the mean values of both soil pH in water and CaCl2 were significantly (p>0.05) different between soil parent materials. The soils are low in organic carbon (range; 2.90 to 7.25 g/kg) in all the studied soils. The mean values of exchangeable bases and CEC were not significantly (p>0.05) different by soil parent materials. The mean values of the different forms of oxides were significantly different (p>0.05) by soil parent materials. The mean values of total sulphur and organic in all soils from three parent materials were significantly different (p > 0.05). The values of inorganic sulphur (Org.S) ranged from 18.33 to 123.78 mg/kg in all the soils across three parent materials, however the mean values were not significantly different (p>0.05). The results revealed that sulphate desorption decreased with increasing shaking time (range; 34.96 to 19.09 mg/kg) in all the studied soils. Rate of desorption was also characterized by an initial rapid desorption with > 65% being desorbed in the first 30 minutes which was considered as good index for describing S desorption maximum followed by a slow release that progressed gradually up to 240 minutes. The adsorption-desorption processes were irreversible and hysteretic in nature. The trend of magnitude of rate of desorption by the soil parent materials was in descending order: CF>BCR>KKF. The study showed that the parabolic diffusion and first-order models were found to describe S desorption data satisfactorily as characterized by relatively high R2 values and lowest S.E values by soil parent materials, respectively. Comparison of R2 values of the best isotherm equations indicated that both Langmuir and Freundlich isotherm models were suitable to describe S desorption data in all the studied soils, as can be seen from R2 greater than 0.98. However, in view of the low SE, Langmuir equation gave a better fit to experimental data in this study. Organic matter had a significant influence on modeling of S desorption in these soils. The results also revealed that the BC used in this study did not have significant effect on release of adsorb S (p>0.05). Based on the results, can be concluded that rate of sulphate desorption by these soils are time-dependent and mainly controlled by diffusion-controlled phenomena. It is recommended that sulphur management practice in the farm should be tied up with OM management. It is also recommended that affinity of BC to release plant nutrients should be tested before applying to soils as amendment.
The essentiality of sulphur (S) for plant growth has been known from the time of Liebig
(Tabatabai, 2005a), but compared with other major nutrients such as nitrogen (N), phosphorus
(P) and potassium (K) it has, until recently, received little attention. Plant adsorb sulphate (SO42-)
from the soil solution, therefore replenishment from organic and adsorbed sources is important in
maintaining sulphate supply to the plant (Sumner, 2000).
Importance of S as a plant nutrient was largely overlooked in soil science research, mainly
because the incidental supply of S via deposition and S- containing N and P fertilizer was usually
sufficient to meet crop demands. However, since concerns about intensive continuous cropping
were adopted among farmers in the decades, sulphur stock has decreased remarkably in some
soils in the world. In the 1980s, issues of acid rains were raised in Nigeria (Osu et al., 2013), and
sulphur emission from power plants and industries has significantly declined which has led to
major causes of S deficiency in some soils.
Over the last 2 decades, farmers deviate from using sulphur rich fertilizers to high analysis
fertilizers that contain less amount of sulphur which has masked many latent or incipient sulphur
deficiencies in cultivated land in Nigeria (Raji, 2008). The reduced input of S combined with
intensified farming and larger S removal in harvests depleted the S stocks in soils and in the
1990s, sulphur deficiency began to surface (Ceccotti, 1996).
Sulphur deficiency can cause marked yield loss and reduce the quality of crops and forage in
some soils of the world (Wang et al., 2002; 2008; Zhao et al., 2006a). In addition, S deficiency
decreases resistance to pathogens (Falk et al., 2007; Walters and Bingham, 2007) and reduces N
utilization efficiency (Ahmad and Abdin, 2000).
1.1 Problem statement
As sulphur is relatively cheap element, fertilization with S is now becoming standard practice
(Boye, 2011). However, knowledge of how to optimize the amount and timing of S fertilization
is still insufficient. Sulphur fertilization can decrease selenium (Se) content in crops, which is
problematic for animal and human nutrition in Se-poor soils (Stroud et al., 2010). Sulphur can
also induce eutrophication in freshwater wetlands, as the precipitation of iron-sulphide releases
iron-bonded phosphates (Lamers et al., 2002), the understanding of the kinetics of SO42-
desorption is critical in preventing such problems.
Sulphur is widely distributed in nature in both, organic and inorganic forms. Inorganic S is in the
readily available fraction for root uptake, or may be adsorbed on to soil colloids, but represents
an average of less than 5% of total S in the soil. The majority of S (> 95%) in soil is bound to
organic molecules and is only indirectly available to plants (Kertesz and Mirleau, 2004). In
You either get what you want or your money back. T&C Apply
Share a Comment
You can find more project topics easily, just search
SIMILAR SOIL SCIENCE FINAL YEAR PROJECT RESEARCH TOPICS
1. MAXIMIZING YIELD AND NET RETURNS TO NITROGEN, PHOSPHORUS AND POTASSIUM FERTILIZER APPLICATION IN RICE (Oryza sativa. L) PRODUCTION ON LOWLAND SOILS» ABSTRACT Rice (Oryza sativa .L) is an important staple and source of income for farmers in Nigeria. Current fertilizer recommendations for rice do not...Continue Reading »
95 pages | 18 hits | Source: SOIL SCIENCE
2. RESPONSE OF GROUNDNUT (Arachis hypogaea L.) TO RHIZOBIA INOCULATION, NITROGEN AND PHOSPHORUS FERTILIZERS ON AN ALFISOL IN THE NORTHERN GUINEA SAVANN...» ABSTRACT Groundnut (Arachis hypogeaa L.) productivity in Nigeria has remained low over the years due to the inherent low fertility status of the soils...Continue Reading »
111 pages | 0 hits | Source: SOIL SCIENCE
3. OPTIMIZED INORGANIC FERTILIZER APPLICATION ON SORGHUM YIELD AND NITROGEN USE EFFICIENCIES IN THE NIGERIAN SAVANNA» ABSTRACT Sorghum (sorghum bicolor (L.) Moench) is an important staple food grain that is grown among smallholder farmers. The yield is low due to inhe...Continue Reading »
105 pages | 69 hits | Source: SOIL SCIENCE
4. EFFECT OF LAND USE AND SLOPE GRADIENTS ON SELECTED PROPERTIES AND SOIL QUALITY OF AN ALFISOL IN AFAKA FOREST, NORTHERN GUINEA SAVANNA OF NIGERIA» ABSTRACT Land use changes from forest into cultivated ecosystems result in negative impact on soil structure and quality. The purpose of this study wa...Continue Reading »
122 pages | 61 hits | Source: SOIL SCIENCE
5. ASSESSMENT OF SOME MACRONUTRIENT STATUS AND MICROBIAL DIVERSITY IN PALM OIL MILL SLUDGE DUMPSITES AND ITS IMPLICATIONS ON SOIL FERTILITY» ABSTRACT The composition of palm oil mill sludge pH 4.2+0.09 was acidic while organic matter, 39.3+0.27, total N 31.2+001, total P 10.4+0.05 and EC 1....Continue Reading »
52 pages | 116 hits | Source: SOIL SCIENCE
» TABLE OF CONTENT Title page i Certification ii Dedication iii Acknowledgement iv Table of content v Abstract x CHAPTER ONE 1.0 Introduction 1 1.1 Obje...Continue Reading »
62 pages | 354 hits | Source: SOIL SCIENCE
7. NITROGEN MANAGEMENT OPTIONS FOR IRRIGATED AND RAIN-FED RICE (OryzasativaL. )VARIETIES IN SUDAN SAVANNA OF NIGERIA» ABSTRACT RiceisoneofthemainstaplefoodcropsanditsdemandisrapidlyincreasinginWestAfrica,hencethereisneedtoincreaseitsproductionatlowerproductioncoststhr...Continue Reading »
114 pages | 65 hits | Source: SOIL SCIENCE
» ABSTRACT Evaluating the distribution (species and concentration) of chemical elements in the biosphere (rock, soil, water, plants, and air) and the st...Continue Reading »
152 pages | 61 hits | Source: SOIL SCIENCE
9. RESPONSE OF GROUNDNUT (Arachis hypogaea L.) TO RHIZOBIA INOCULATION, NITROGEN AND PHOSPHORUS FERTILIZERS ON AN ALFISOL IN THE NORTHERN GUINEA SAV...» ABSTRACT Groundnut (Arachis hypogeaa L.) productivity in Nigeria has remained low over the years due to the inherent low fertility status of the soils...Continue Reading »
111 pages | 0 hits | Source: SOIL SCIENCE
10. EFFECT OF LONG TERM ROTATION, NITROGEN FERTILIZER AND TILLAGE ON SOIL QUALITY AND MAIZE YIELD IN THE NORTHERN GUINEA SAVANNA OF NIGERIA» Abstract A long term field experiment was established in 2003 at the Institute for Agricultural Research, (I.A.R) Samaru, northern Guineasavannaof Nig...Continue Reading »
130 pages | 74 hits | Source: SOIL SCIENCE